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Computers in Introductory Chemistry Laboratories
A Proposal Submitted to NSF in June 2000
funded May 2001-April
2003
In June 2000 we submitted to NSF a proposal to purchase computers and laboratory interfacing for the introductory chemistry laboratories. This document is an attempt to show the logic of that request.
edited: January 21, 2001 (This is being revised, August 2004)
comments to: Paul Endres
file: nsf/nsf5_HPC.htm
Introduction:
For some time we have been trying to find a way to bring computerized data collection to the general chemistry course. There are some serious problems that need to be resolved.- cost (purchasing computers, but also developing software and maintenance)
- space (including where computers are placed)
- security (from theft, but also from laboratory chemicals which are tough on electronics)
- accessories (30-50% of the cost of a typical installation is devoted to sensors and interfacing with the computer.)
- actual experiments designed to intelligently use computers
- students take experimental materials to the computer work site
- we have up to 60 students in these labs
- 60 computers is unrealistic
- working individually on alternate weeks would require 30 computers
- basic cost-- about $2500 for computer and lab interfaces (about $75,000)
- each standard computer needs about 4 ft of table top
- we'd need about 120 feet of space around the room
- there isn't that kind of space available in the general chemistry lab
- we still need about 4 ft of bench space
- that's over half of the area for one student work station
- we might build a stand to keep most of the computer off the table top
- however, we need to keep the computer safe (from water, reagents, ring stands)
We could, of course, use fewer computers
- have students work in groups of two or four
- to have computer use limited to 20 minutes/lab so same machine can be shared by 2-3 groups
- This can be done, but it severely limits the role of the computer in experiments
- space needed per unit is much smaller
- cost is generally higher than for standard PC's
- ($1500-2000 for computer; $250 accessories)
- laptops are generally easier to damage, harder to get repaired
- laptops are harder to keep secure (easier to steal)
- laptops might be harder to keep safe (easier to move into a region of chemical danger)
We were not satisfied with this approach:
- programming is extremely awkward
- dumping data to a PC is possible, but not convenient
- data display is tiny
- computational options are surprisingly limited
- students familiar with computers would see this as a very backwards technology
- PDA-- Personal Data Assistant like the Palm (TM) devices
- HPC-- Handheld Personal Computers
- Obviously these are smaller and fit our space well
- They are portable and could be kept relatively secure when not in use
- They are generally designed for a somewhat more rugged environment than PC's and laptops
- They are considerable less expensive than PC's ($100-500)
- They have communication features that we could use effectively
- They have no commercial software that can handle laboratory situations
- They are programmed using a specialized programming language
- We could expect a steep learning curve and a long preparation time before we could use such devices in the lab.
- Most students would be unfamiliar with the specific device and would have to learn its operation
- Most PDA's actually have a tiny screen with modest capability
- this means the screen has the look and feel of conventional computing activity
- a programmer can develop software using standard computing languages like Visual Basic
- the screens generally have larger size and better resolution than most PDA's
Let's look at some typical applications. Let us also ask some very
specific questions.
1. What are the (chemistry) concepts that the experiment develops?
Calorimetry
- Dissolve a metal (Ca, Mg, Zn, Fe) in acid
- Measure the temperature rise
- store temperature vs.. time data
- display temperature vs.. time graph
- Compute the Enthalpy change in the reaction.
- The real time graph shows additional information
- student gets experience extracting information from graph
- actually see the rate of the reaction
- could examine the effect of surface area
- compare time for large pieces vs granualar metal samples
- can see heat loss
- can see cooling after the reaction
- due to both heat losses (insulation) and to evaporative cooling
- this would probably not be noticed with thermometer
- time to focus on interpretation and calculations
- time to include a calibration run
- time to make several runs and comparisons
Titrations
Acid-Base Titration Curves
We do this now with conventional glassware and pH meter.
- typically make 10-20 additions of titrant
- read and record pH
- then plot graph
- finally interpret graph
- each run typically takes 30 minutes
- students likely to get 2-3 runs in a period.
- allows many more data points to be collected, leading to smoother and well defined graphs
- minimizes tedium and transcription errors
- data appears in real time
- experiment provides data initially as a visual image
- student is free to focus on data, to try to predict remainder of the curve
- could be a 2-4 minute run
- it would be realistic to do 5 (or even 10) different runs for comparison
- strong and weak acids, strong and weak bases
- with good graphics, endpoints of weak acid-weak base can be determined
- polyprotic acids
- mixtures (bicarbonate, carbonate), (HCl and acetic acid)
- strong and weak acids, strong and weak bases
- Again, comparison of runs begins with a visual image (curve) with clear qualitative differences
Titrations
Other than Acid/Base by pH
Could monitor temperature during an acid base titration curve
- can actually use both temperature and pH probes and plot both
- this is rapid process
- results show up immediately as visual image
- would be too tedious to collect many data points
- would need to do more slowly and heat loss is more of a factor then
- complexing reagents, precipitates, neutralization
Kinetics
Can expect to monitor concentration of one species throughout a reaction
- typically be colorimetry or spectrophotometry
- could also use a species selective electrode
- can monitor heat produced by reaction
Vapor Pressure of a Liquid
- Simple pressure sensor can record pressure vs.. time.
- Small amount of liquid added to a closed flask connected to the probe
- As liquid evaporates, pressure rises
- Pressure levels off when the equilibrium vapor pressure is reached
- Again, process produces a real time visual image (graph)
- Process is rapid (2-5 minutes)
- Could be one part of a larger experiment on gases
- Could be run at several temperature to determine enthalpy of evaporation
- Could be done with conventional equipment
- pressure measurement is more difficult and slower
- of course, same probe could be set up for a voltmeter
- would only get a few data points
- would rely on initial and final values, not on curve
- pressure measurement is more difficult and slower
Important concepts to be examined: